Chemical bonding: ionic, covalent and metallic, compared

Bonding questions ask you to predict properties from structure. Get the electron count right and the shape, polarity and boiling point follow.

What this covers

  • Ionic, covalent and metallic bonding
  • Lewis dot structures
  • VSEPR shapes and bond angles
  • Polarity and dipoles
  • Intermolecular forces

Worked example

Problem

Predict the shape and bond angle of NH₃.

  1. 1
    Count electron domains
    Nitrogen has three bonding pairs and one lone pair β€” four domains.
  2. 2
    Base geometry
    Four domains give a tetrahedral arrangement.
  3. 3
    Account for the lone pair
    The lone pair repels more strongly, compressing the angle from 109.5Β°.
Answer: Trigonal pyramidal, bond angle β‰ˆ 107Β°

Mistakes that cost marks

  • Counting only bonding pairs and ignoring lone pairs.
  • Assuming polar bonds always give a polar molecule.
  • Calling hydrogen bonding a covalent bond.

Questions students ask

How do I know if a molecule is polar?

Draw the shape, then add the bond dipoles as vectors β€” symmetric shapes cancel.

Practise structure and bonding until it sticks

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